Equilibrium Constant Calculator

Determine the equilibrium constant for reactions of the form aA + bB ⇌ cC + dD, with optional conversion between Kc and Kp.

Kc

0.25

How to Use This Calculator

1

Identify stoichiometry

Balance the reaction and record coefficients for each species.

2

Provide concentrations or partial pressures

Enter equilibrium values of reactants and products (mol/L or atm).

3

Select Kc or Kp mode

Choose Kp for gas-phase reactions where partial pressures are known and supply temperature and Δn.

4

Review results

The calculator displays Kc and optionally Kp, offering quick insight into reaction equilibrium.

Formula

Kc = Π([products]^{stoichiometry}) / Π([reactants]^{stoichiometry})

Kp = Kc (RT)^{Δn}

Δn = Σ ν_products(g) − Σ ν_reactants(g). R is 0.082057 L·atm·mol⁻¹·K⁻¹ when working with atm and liters.

Example

For N₂ + 3H₂ ⇌ 2NH₃ (Δn = −2) with concentrations 0.2, 0.3, 0.15, 0.1 M, Kc = (0.15²)/(0.2 × 0.3³) ≈ 1.39.

Full Description

Equilibrium constants quantify the composition of mixtures at equilibrium. Kc uses molar concentrations, while Kp relies on partial pressures for gas-phase systems.

This calculator assists with coursework and practical chemistry by handling stoichiometric exponents and converting between Kc and Kp when temperature and Δn are known.

Frequently Asked Questions

Do I need to include pure solids or liquids?

No. Pure solids and liquids have activity 1 and are omitted from the expression.

Why are coefficients exponents?

Derived from the law of mass action, each species concentration is raised to its stoichiometric coefficient.

Can I mix concentration units?

All concentrations or pressures must use consistent units (e.g., mol/L or atm) for the ratios to be dimensionless.

What if Δn is zero?

Then Kp = Kc. The equilibrium constant is independent of temperature scaling factors in that case.

Does this handle more than four species?

This version covers a generic four-species reaction. For more species, extend the formula accordingly.